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| Abstract An investigation was conducted to find a simulated cooking load to test the thermal efficiency of portable convection ovens, which would reproduce values obtained with typical foods cooked in a series of commercially available ovens. In an extended survey of volunteer convection oven users, a 0.4-lb loaf cake in an aluminum foil pan, as a "medium" load; and a 1.5-lb meat loaf in a glass loaf dish, as a "heavy" load. Loads tested included sand-water mixtures, cotton cloth in water, starch dough in various containers, and aluminum test blocks, both blackened and shiny. The thermal efficiencies obtained with the starch dough baked in a standard chemical crystallization dish correlated best with the average of the efficiencies for the three food loads. A close second choice for the simulated cooking test load would be either the 2.47-lb or 5.24-lb blacked aluminum block heated for 30 minutes. |
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Oat, Grain, Moisture, Oat, Grain, Thermal Conductivity Liquid-to-particle convective heat transfer coefficients are useful in developing aseptic food processing systems. They were determined for continuous flow through a holding tube at 115.5 degrees C using liquid crystal and relative velocity methods with sodium carboxymethylcellulose solution to simulate non-Newtonian fluid characteristics. An on-line tube viscometer was used for in situ estimation of rheological characteristics. Minimum and maximum values of h(fp) determined from the liquid crystal method ranged from 986 W/m(2o)K to 2270 W/m(2o)K, (Nusselt numbers from 26.4 to 54.6). Values from the relative velocity method ranged from 1143 to 2270 W/m(2o)K (Nusselt numbers from 33.2 to 63.1) when using the Ranz and Marshall relation, and from 598 to 1456 W/m(2o)C (Nusselt numbers from 13.6 to 24.1) with a flat-plate correlation. Heat transfer coefficients increased significantly with decreasing carrier medium viscosity and decreasing particle-to-tube diameter ratio and increased with flow rate.
ABSTRACT: Liquid-to-particle convective heat transfer coefficients (hfp) were determined in non-Newtonian carriers during continuous flow using three different experimental techniques. Process parameters such as carrier viscosity, flow rate, particle size, and radial location were found to influence hfp values. Minimum and maximum values of hfp were found to be 363 W/m2 degrees C and 2010 W/m2 degrees C respectively over a fluid Reynolds number range of 14.5 to 798. Significant fluid-particle relative velocities (0.02 to 0.19 m/s) were measured during visualization studies of fluid flow around a moving particle. The relative velocity and consequently hfp values were influenced by particle radial location and the local flow field about the particle. Internal Temperature, Thermal Property, Heat Transfer,
Grapefruit, Thermal Conductivity, Thermal Diffusivity, Specific
Gravity, Moisture This paper describes a mathematical procedure to determine the lethality in a continuous sterilization system for foods containing large particles. A computer program to predict the temperature distribution within the flowing particles and heat lethality was developed using finite difference equations. The convective heat transfer coefficient between fluid and particles was experimentally estimated by means of a model system consisting of an immobile potato cube surrounded by a continuously flowing fluid. To verify this approach, a tubular heating-holding pilot plant was used for processing potato cubes in a NaCl solution. A biological validation of the mathematical model was carried out by inoculating the potato cubes with yeast cells and comparing the experimentally measured lethality values with those calculated using the computer program. Quite a good agreement was obtained between the model predictions and the experimental findings.
ABSTRACT: Thermal conductivity (TC) of potato was calculated from heat penetration into cylindrical samples between 50 and 100 degrees C. TC ranged from 0.545 to 0.957 W/m degrees C for potatoes (cv Kennebec) specific gravity 1070 kg/m3 and moisture 80%. Experimental values agreed with reported values. TC, k, varied with temperature in a quadratic polynomial form, and an empirical relationship was estimated. A model based on the concept of thermal resistances in parallel was compared with experimental results. These were used in a heat transfer model that simulated potato frying. Measured and simulatead time-temperature curves showed good agreement. .
ABSTRACT: The effects of entrapped air on the heating rate, lethality and cold spot in bricks packaged in retort pouches were determined using silicone rubber bricks (10 X 14.5 X 2cm), with 5 thermocouples positioned from the geometric center-point to near the top surface. The packaged bricks were processed in steam/air media at two temperatures (121.1 degrees C and 115.6 degrees C) and two levels of superimposed air over-pressure (corresponding to 65% and 75% steam). With the exception of the highest level of over-pressure, (121.1 degrees C, 65% steam content), entrapped air volumes > 20 mL reduced heating rates and lethality, and shifted the cold spot from the geometric center. At 60 mL of entrapped air the point of least lethality was near the brick surface.
ABSTRACT: With the current interest in chemicals production from biomas and in view of the emerging pulping processes, the hydrolysis of lignocellulosics is being considered as a promising industrial approach. Since hemicellulose is more readily hydrolyzed than cellulose, most processes include a prehydrolysis step to remove pentosans prior to the main hydrolysis of cellulose to glucose. However, the mechanism of solid-phase acid-catalyzed hydrolysis has not been elucidated and it is impossible to predict the extent of reaction a priori. Having the goal to design reactors, engineers need empirical rate equations. A series of kinetic data available in the literature have been compiled and different kinetic empirical models were analyzed in order to simulate the dilute-acid prehydrolysis of xylan-containing materials. The objective of this paper is to provide profiles of xylan removal and xylose production as a function of a few process variables such as: preheating time, heating rate, acid concentration, reaction temperature and reaction time. Moreover, the influence of biomass species as well as the type of reactor were studied to understand the different solubilization profiles obtained. Other variables such as biomass concentration and particle size were also analyzed. The cellulose dissolved during the prehydrolytic stage was calculated to determine the prehydrolysis selectivity. Heat Transfer, Nonnewtonian Fluid, Newtonian Fluid, Jacketed Kettle, Thermal Conductivity Heat Transfer, Thermal Conduction
ABSTRACT: A finite-difference model was used to predict the moisture migration in shelled peanuts during transportation in sealed railroad tank cars. The roof of the railcar received solar radiation heating during the day and radiative cooling at night. Energy and mass balances were used along with a simplified zone analysis of radiative heat transfer to determine the conditions in a headspace above the peanuts. The model agreed well with temperature measurements from three tests with an experimental railcar. The long-term moisture migration from the natural convection currents was not sufficient to cause any excessive moisture accumulation in the railcar. The model simulations indicated that the diurnal heating and cooling cycle in the headspace was the primary cause of moisture accumulation at the top of the railcar.
ABSTRACT: A model was developed to predict heat and moisture transfer due to natural convection and diffusion in arbitrarily shaped two-dimensional porous media. Boundary conditions were diurnally varying ambient temperature on the outside of walls with moderate Biot number. Other important boundary conditions were developed for typical storage and transportation situations. A two-energy equation model was used to allow for the difference between the fluid and solid temperatures and its effect on mass transfer in the porous medium. The governing equations were solved with a finite-difference method in a generalized coordinate system using a stream function formulation. It was found that the energy and moisture transport equations were best solved using a modified Crank-Nicolson method that was developed to control the tendency for instability caused by the source terms in these equations. All of the boundary conditions that were developed worked satisfactorily. The two-energy equation model predicted small differences between the fluid and solid particle temperatures and natural convection only impacted the temperature solution significantly in the upper comers of the porous media. Thermal Conductivity, Freezer, Heat Transfer Coefficient, Cod, Heat Penetration Pseudoplastic, Newtonian Fluid, Eckert's Consideration, Applesauce Viscosity, Banana Puree Viscosity, Viscosity, Applesauce Thermal Conductivity, Applesauce Specific Heat, Applesauce Heat Transfer, Applesauce Density, Banana Puree Thermal Conductivity, Banana Puree Specific Heat, Banana Puree Heat Transfer, Banana Puree Density, Ammonium Alginate, Thermal Property
ABSTRACT: The thermal behavior of a conductive canned food during retorting was represented using an input-output linear system, with a finite order N, and a time-delay. The input of the system was the retort temperature, the output was the temperature at the thermal center of the can. This model was applied for a typical sterilization process composed of two isothermal steps. The can internal temperature was expressed as a sum of N exponential terms in which appeared the constant holding retort temperatures, the come-up and come-down times and N pairs of heat penetration parameters identified in a preliminary experiment. The model was tested on a potato mash packed in metal cans processed in a vertic still retort. Temperatures estimated by the model agreed closely with those measured during thermal processing. . Thermal Conductivity, Heat Capacity, Thermal Diffusivity
ABSTRACT: To characterize heat penetration curves in food processing, 'f' and 'j' values are generally used for conduction as well as convection heating. Such asymptotic semilogarithmic time-temperature relations have been mathematically proven only for the restricted cases of conduction heating in regular geometries and for forced convection heating. This study mathematically justifies and interprets such approximation in the case of conduction heating in arbitrary shapes. In the case of natural convection heating, the complicated nature of the governing equations and the flow instabilities are discussed and it is concluded that such a semilogarithmic time-temperature relation is unlikely from physical as well as mathematical considerations, although, both the theoretical (numerical) solution as well as the experimental data for the natural convection heating can be empirically approximated to such a semilogarithmic form over small ranges of processing time for practical purposes. .
ABSTRACT: Direct resistance heating (DRH) offers the chance to process solid and liquid foods at the same rate, avoiding the delay due to thermal conduction which prevents the use of HTST technologies on particulate foods. The attempts to exploit the advantages of DRH in food processing over the last century are reviewed. A successful DRH unit requires non-contaminating electrodes which have a good contact with the food material, control of the food heating rate and, if sterilisation is required, an efficient aseptic packaging process. Recent developments in these three areas mean that the advantages of direct resistance heating can now be commercially exploited. Thermal Diffusivity, Chicken A La King, Chicken Heat Transfer Coefficient, Thermal Property, Thermal Diffusivity, Chicken A La King, Thermal Conductivity, Specific Heat Canning, Thermal Property Canning, Thermal Property P>
Fernandez-Martin, F. and Montes, F. 1977. Thermal conductivity of creams. Journal Dairy Research 44: 103. Freezing Rate, Thawing Rate, Ice Crystal Growth, Specific Heat, Density, Thermal Conductivity, Thermal Diffusivity, Heat Transfer Purpose/Objectives: to determine standards for food times and temperatures and amount of food consumed.
ABSTRACT: The present study considered the application of on-line computer data acquisition and control to the thermal processing of foods in hermetically sealed containers. A pilot-scale steam retort was fitted with a control system based on a desk-top computer. Under computer control, the retort could be operated conventionally as a series of timed sequential process steps or the process time could be based on a target lethality defined by the operator. In the latter case, feed-forward prediction of the cooling period lethality was used. One control program was based upon thermocouple data derived from test cans. The lethalities determined in real time were compared with those derived numerically by simulating heat penetration by the method of finite differences. The two control programs (thermo-couple-in-can and numerical) were compared for their ability to respond to process deviations. The statistical aspects of computerized retort control were also examined
. Thermal Conductivity, Human, Fat, Thermal Conductivity, Thermal Conductivity, Beef, Meat, Fat, Thermal Conductivity, Beef, Meat, Thermal Conductivity Computer, Thermal Conductivity, Heat Transfer, Thermal Processing Thermal Conductivity, Beef, Pork, Lamb Leg, Veal, Leg, Moisture, Beef, Grade
ABSTRACT: Abstract: Mathematical models were developed to predict the temperature and mass histories of meatballs (4.7 cm diameter, 60 g) during forced convection baking, natural convection baking (broiling), and boiling. The finite difference method was used to solve the simultaneous heat and moisture transfer equations using constant transport properties and the continuous system modeling program (CSMP). Surface heat transfer coefficients were determined by the transient temperature measurement method, with values of 23.0, 9.0, and 4518 W/m2 K, respectively, for forced convection baking, natural convection baking (broiling), and boiling. Thermal and moisture diffusivity values for meatball cooking processes were estimated from the experimental data by minimizing the root-mean-square of deviations between the observed and predicted temperature and moisture histories. The thermal diffusivity values were 1.8 X 10-7, 1.9 X 10-7, and 1.6 X 10-7 m2/s for meatball cooking during forced convection baking, natural convection baking, and boiling, respectively. Moisture diffusivities of the meatball for the first two processes were 3.9 X 10-8 and 2.5 X 10-8 m2/s, respectively. The average root-mean-square of deviations between the observed and predicted temperature histories (2-90 degrees C) ranged from 3.0 to 5.1 degrees C for the cooking processes, and between the observed and predicted meatball mass, accounted for the moisture loss only, ranged from 0.04 to 0.19 g. ABSTRACT: This review examines the four physical avenues of heat transfer affecting the thermal equilibrium of low birthweight infants, and the risk of hypothermia. Hydrocarbon, Thermal Property, Hydrocarbon, Viscosity, Thermal Conductivity, Thermal Diffusivity Mushroom, Thermal Property, Freeze-Dried Mushroom Temperature, Mass Average Temperature, Geometric Center, Thermal Property
ABSTRACT: A commercially available lithium bromide-water absorption cycle air conditioner was operated as a solar-driven heat-pump. Energy from water heating flat-plate solar collectors was used as the driving force for the system. Efficiency characteristics were evaluated for four operational modes: (1) a regular heating/cooling mode, (2) a closed-cycle cycle operation, (3) a latent-to-sensible heat transfer mode where a controlled moisture load was introduced, and (4) a latent-to-sensible heat transfer mode where the moisture load was from drying grain. The system was evaluated for both clear and partly cloudy weather conditions. Coefficients of performance followed a pattern very similar to the temperature pattern in the hot water loop of the generator. The coefficients of performance for cooling (COPc) ranged from 0.55 to 0.80, generally decreased as generator inlet water temperature increased, increased as condenser inlet water temperature increased, decreased as air temperature entering the evaporator decreased and decreased as moisture load at the evaporator decreased except for regular heating/cooling operations. Condenser inlet water temperature showed stronger effects on COPc than did generator inlet water temperature. Coefficient of performance for heating (COPh) ranged from 1.40 to 1.86, generally decreased as generator inlet water temperature increased, decreased as condenser inlet water temperature increased, increased as air temperature entering the evaporator increased, and increased as moisture load at the evaporator increased. Moisture load influences were statistically the same for all four modes of operation and air inlet temperature generally had a stronger effect on COPh. than did generator inlet water temperature, but less effect than condenser inlet water temperature. he latent-to-sensible heat transfer operational modes were more efficient than the regular heating/cooling or closed-cycle modes. Also, it was estimated that solar-driven absorption cycle heat pump grain drying can save as much 40% on electrical energy requirements compared to a compressor driven heat pump grain drying system, 60% compared to electrical resistance heating and better than 70% compared to LPG and oil heating. Abstract Breakdown of heat-labile constituents in foods is approximated as first-order chemical reaction, mathematically similar to the destruction of bacteria. Experimental time/temperture histories of several processes were each transformed into a single degradation value with known or assumed temperature-response (z) values. With this simple procedure, processes and processing steps that were major contributors to thermal degradation of desirable attributes could be identified and modified to minimize loss of quality. Examples are given to illustrate the procedure and some of its applications. ABSTRACT: Based on thermal degradation kinetics and heat transfer expressed as the Ball formula method, a simplified approach was used to optimize sterilization processes for thermal softening of white beans (Phaseolus vulgaris, subsp. nanus Metz., variety Manteca de Leon). Constant retort profiles in a still and end-over-end rotary water cascading retort (Barriquand Steriflow) were used. Quality attributes of beans processed at the optimum were evaluated by a trained taste panel and by a tenderometer. Both approaches could distinguish (P <0.01) between attributes of products from optimal rotary and still processes. end-over-end rotation resulted in faster heat penetration and better quality retention of beans. texture of white beans processed at 4 degrees or 8 degrees c from the optimal temperature could be distinguished (p <0.01) by the sensory panel and by the tenderometer.
ABSTRACT: Based on thermal degradation kinetics and heat transfer expressed as the Ball formula method, a simplified approach was used to optimize sterilization processes for thermal softening of white beans (Phaseolus vulgaris, subsp. nanus Metz., variety Manteca de Leon). Constant retort profiles in a still and end-over-end rotary water cascading retort (Barriquand Steriflow) were used. Quality attributes of beans processed at the optimum were evaluated by a trained taste panel and by a tenderometer. Both approaches could distinguish (P <0.01) between attributes of products from optimal rotary and still processes. end-over-end rotation resulted in faster heat penetration and better quality retention of beans. texture of white beans processed at 4 degrees or 8 degrees c from the optimal temperature could be distinguished (p <0.01) by the sensory panel and by the tenderometer. . This paper describes the development of a two-dimensional heat and mass transfer model of beef carcass chilling. The model includes thermal properties as functions of temperature and composition. The carcass was divided into five zones, i.e. round, sirloin, loin, rib and chuck, and the carcass cross-sectional structure within a zone was considered uniform. The model was solved using finite element method. Temperature and mass histories were collected for three chilling schemes to validate the model. The simulated results are in good agreement with the observed data, and the predicted temperature and mass histories within 2.7 degrees C and 0.4%, respectively. Abstract A laboratory experiment was performed to investigate the interaction between energy source and container material in surface cooking oerpations as determined by evenness of heating, speed of heating, and heat retention. Energy sources were a conventional gas burner; a conventional electric coil; an electric resistance heater and induction coil, both under glass-ceramic; and a solid electric element. Cookware of thin- and heavy-gauge aluminum, porcelain enamel over thin-gauge steel, heavy-gauge stainless steel with a thick aluminum heat core, and glass-ceramic was combined with each of the enrgy sources to complete a cooking system. A General Linear Models procedure was used to assess statistically the impact of each variable on test results. Duncan Multiple Range tests were performed to identify statistically significant differences between systems. Heavy-gauge aluminum and heavy-gauge stainless steel with a thick aluminum heat core produced the most even browning of crepes in all cooking systems. Regardless of the cookware used, the induction unit, gas burner, and conventional electric coil boiled water more quickly than did the other energy sources, while the solid element and the electric resistance coil under glass-ceramic retained more heat. Most of the published methods for estimation of freezing time require thermal properties of the product and any relevant heat transfer coefficients between the product and the cooling medium. However, the difficulty of obtaining appropriate thermal data for use in industrial freezing of food has been pointed out. The authors have developed a new procedure for estimating freezing time, a procedure which does not require the knowledge of thermal data of the food being frozen. The new procedure, however, requires analytical solution of the heat conduction equation. In this paper, a simplified approximate equation which has an analytical solution was derived to describe the time/temperature profile with an acceptable accuracy during freezing aqueous solution of sodium chloride. At the terminating stages of freezing, on the other hand, the temperature profile was found to be described by an analytical solution of a heat conduction equation with constant thermal properties. Hence, a two-stage mathematical model was proposed for freezing which is applicable to the authors' new procedure for on-line prediction of freezing time.
Existing methods of estimation of freezing time require data on thermal properties of the product and any relevant heat transfer coefficients. This paper describes a new procedure for estimating freezing time; a procedure that does not require the knowledge of thermal data of the food being frozen. This procedure collects time/temperature data from the early stages of cooling, analyzes these data to determine system parameters associated with the heat conduction equation and predicts the time/temperature profile in the remainder of the freezing process using these system parameters. This system has been validated via experiments on freezing fish meat as well as wheat flour dough.
ABSTRACT: To understand the influence of frying oil's physical properties on heat transfer, heat transfer coefficient and oil viscosity were measured for combinations of oil type, temperature, and condition. The lumped capacity method for heat transfer in a high thermally conductive metal gave convective heat transfer coefficients. A capillary viscometer in a convective airheater provided viscosity data at frying temperatures. Frying time and oil temperature significantly affected viscosity. Oil viscosities were not statistically different between fresh and 12 h frying oil or 12 and 24 h frying oil, while between the remaining frying times the oil viscosities were statistically different. Corn oil viscosity showed the greatest increase over 36 h and the highest correlation between viscosity and heat transfer coefficient (-0.959) .
ABSTRACT: To understand the influence of frying oil's physical properties on heat transfer, heat transfer coefficient and oil viscosity were measured for combinations of oil type, temperature, and condition. The lumped capacity method for heat transfer in a high thermally conductive metal gave convective heat transfer coefficients. A capillary viscometer in a convective airheater provided viscosity data at frying temperatures. Frying time and oil temperature significantly affected viscosity. Oil viscosities were not statistically different between fresh and 12 h frying oil or 12 and 24 h frying oil, while between the remaining frying times the oil viscosities were statistically different. Corn oil viscosity showed the greatest increase over 36 h and the highest correlation between viscosity and heat transfer coefficient (-0.959).
ABSTRACT: Movement of oxygen and subsequent microbial development and heating in corn silage were measured over four days at 5, 20, 35, and 50 cm from the exposed face in laboratory-scale (60 X 15.5 cm diameter) PVC silos. In all six trials, most microbial activity occurred at the 5-cm level. Acetic acid bacteria initiated heating in all trials although yeasts were significant in two trials. Bacilli were not important until silage pH was above 5 and were associated with a secondary temperature rise in four trials. Oxygen entering the silage at the open face was utilized principally near the face, and temperatures above 40 degrees C were observed only at the 5-cm level. Heating at 20 cm occurred in all trials, but appeared to result from heat transfer from the active zone rather than from microbial activity at that depth. A diffusion-based, one-dimensional model of aerobic deterioration in silage reasonably predicted oxygen, temperature, and microbial numbers although the predicted progression of deterioration relative to the exposed face was consistently too fast. Model predictions were improved by reducing the calculated porosity for diffusion by 30%. AbstractPyrolysis at 700C of a technical grade of sodium dodecyl sulfate that contained an alkyl group distribution of 56.7% dodecyl, 37.5% tetradecyl, and 5.8% hexadecyl resulted in a 65% weight loss and produced 47% of condensable material and 18% of noncondensable gases (largely S)2). The condensable products consisted of the corresponding isomeric alkenes, primary alcohols, and ethers. A substantial amount of the mixed ether, dodecyl tetradecyl ether, was formed along with didodecyl and ditetradecyl ethers. In a cytotoxicity screening procedure using cultured Hamster embryo cells, some of the condensable pyrolyzate components were found to be more toxic than aniline. An apparatus was developed that allowed for end-over-end rotation of cans during processing in a modified still retort. Cans were rotated in a horizontal and vertical position using a variety of guar gum solutions and rotating speeds. Average values of heat transfer coefficient (h) were found to increase with rotational speed. An increased viscosity caused a decrease in the average h value. Can orientation showed a moderate effect on h. Horizontally positioned cans yielded higher average h values. In 0.45 guar solutions, the average increase in h was 75. A 0.5% solution resulted in a 14% increase in h while the 0.75% guar solution increased h to a lesser degree of only 4%. Statistical analysis determined that each of the individual variables was significant (P <0.01) in affecting the heat transfer coefficient. interactions among variables were also found to affect the h value significantly (p <0.02).
ABSTRACT: The effect of various factors on the heat transfer rates of a canned food model (gelatinized starch) were evaluated during thermal processing in an agitating retort. Process variables were retort temperature (110-130C), rotation speed 10-20 rpm), can headspace (6.4-12.8 mm) and starch concentration (3-4%). Thermal process parameters (heating rate index, fh, and heating lag factor, jch) and the resulting process lethality, Fo and cook value, Co were obtained from time-temperature data obtained during processing for three consecutive runs. Rheological properties and color were experimentally evaluated both before and after each run. Overall heat transfer coefficient (Uo) was calculated from the heating rate index using a lumped capacity approach. The study indicated that fh, jch, Fo and Co were influenced (p <0.05) by all process variables except can headspace. uo, was related to retort temperature, rotation speed and initial apparent viscosity. the best dimensionless correlation for uo was nusselt number (logarithmic scale) versus specific apparent viscosity and froude number (r(2)=0.65) . Transfer functions are a very useful tool to study linear systems with multidimensional heat or mass transfer and/or with boundary conditions variable in time. This study describes different cases where transfer functions have been obtained solving the differential balance of mass or energy by a numerical method of finite differences. The thermal histories and concentration profiles calculated using these transfer functions have been compared to experimental ones.
ABSTRACT: Retorting from the frozen state is attractive with respect to product quality and economy and was investigated in canned bentonite and flaked ham. A two dimensional finite difference model was written in which thermal diffusivity varied with temperature. Heat penetrations were completed with initial temperatures of 0, -5 degrees, -10 degrees, -15 degrees and -20 degrees C. In ham, decreasing initial temperatures resulted in increased lag factors (jh) but did not affect heating rate index (fh). In bentonite, fh but not jh increased. D and Z of Clostridium sporogenes PA 3679 spores were not affected by previous freezing. Sub-freezing initial temperatures were judged to be consistent with safe processes if validated with heat penetration studies .
ABSTRACT: To reduce the time required for product development, to avoid expensive experimental tests, and to quantify safety risks for fresh products and the consequence of processing there is a growing interest in computer aided food process design. This paper discusses the application of hybrid object-oriented and rule-based expert system technology to represent the data and knowledge of microbial experts and food engineers. Finite element models for heat transfer calculation routines, microbial growth and inactivation models and texture kinetics are combined with food composition data, thermophysical properties, process steps and expert knowledge on type and quantity of microbial contamination. A prototype system has been developed to evaluate changes in food composition, process steps and process parameters on microbiological safety and textural quality of foods.
ABSTRACT: Irradiation experiments in freshly killed black papilionids under natural sunlight and minimized wind convection showed that antennae, wings and thorax heat with different warming rates and reach different specific excess temperatures under moderate radiation. While the "low-mass" antennal clubs retain almost temperature of the ambient air, the well-insulated "medium-mass" basal wing veins attain vulnerable excess temperatures after about 15 s when fully exposed, T(equilibr) of antennae is 28 degrees C and of forewing 46 degrees C both after 30 s, T(equilibr) of the thorax is 42 degrees C after 8 min , all at T(ambient) of 26 degrees C and under 54 mW/cm(2). The antennal clubs are optimally suitable for measurement of ambient temperature in spite of being fully exposed to the sun. They are equipped with sensilla basiconica. These poreless sensilla with triads of Type I receptors (typical for thermo/hygroreceptors) and their ultrastructure are described for the first time in butterflies. By scanning the wing veins of free-resting Troides with a calibrated light beam of 1 mm in diameter, a slow wing closing reaction could be evoked at discrete sites along most veins, indicating the existence of a sensory system for increasing temperatures. A heating rate of 2.4-4 degrees C/s of the irradiated wing area was necessary to elicit a response. The applied radiation produced an equilibrium temperature of 39 +/- 3 degrees C at the basal veins A2 and A3 after about 12 s. With axonal filling [CoCl(2)] and electron microscopic techniques multiterminal sensory cells (Type II receptors) are traced and described. Some of them are suggested to function as warm receptors. The different role of the peripheral thermoreceptor systems in thermoregulation is discussed. Abstract Specific heat, thermal conductivity, and thermal diffusivity of whole pigeon pea were determined. Batch-specific heat of the grain is a nonlinear function of both moisture content and temperture in the range of 283-313K and 8-26% dry basis, respectively. A second-order multiple regression equation gives a high correlation between the computed and experimental data. Specific heat of dry solid of pegeon pea is also a nonlinear function of the temperature over the range investigated. Bulk thermal conductivity varies linearly from 0.1358 to 0.1862 W/m-K, whereas thermal diffusivity increases nonlinearly in accordance with a third-order regression equation between 9.037 x 10-8 and 9.673 x 10-8 msquared/sec in the moisture range of 12-26%.
ABSTRACT: Precooked, uncured meat is not widely available to consumers, partially because of associated palatability problems and lack of published information on heat uptake under different industrial conditions. The objectives of this study were to determine the tenderness, extent of lipid oxidation, and total cooking losses in pre- and postrigor beef and pork roasts heated at different rates. The muscles were cooked in stainless-steel, perforated heating chambers at oven temperatures of 150, 200, or 250 degrees C and the temperature rise during and after heating was monitored with a digital temperature recorder. Samples were vacuum-packaged, frozen at -20 degrees C for 45 d, thawed at 4 degrees C for 24 h, and reheated in 60 degrees C water for 1 h. Cooking losses, Warner-Bratzler shear force values, thiobarbituric acid values, and pH were determined. The results provide heating curves for pre- and postrigor beef and pork roasts at three oven temperatures. Prerigor samples of both species were less tender than postrigor samples (P <.05). cooking losses were generally low in prerigor samples of both species compared with postrigor samples (p <.05). all beef samples had relatively low thiobarbituric acid (tba) values before and after storage, whereas pork samples had relatively high tba values before and after storage. results indicate that prerigor cooked roasts shrink less, are equivalent or better in oxidative stability, and are less tender than postrigor cooked roasts under the conditions of this experiment.
ABSTRACT: The thermal properties of potato amylose (degree of polymerization 5,500) and of enzyme-resistant starch (RS) (degree of polymerization 65) from autoclaved maize starch in a concentrated aqueous system (22%, w/w) were studied by differential scanning calorimetry (DSC). Heating of amylose and RS in the DSC instrument to 180 degrees C (heating rate 5 degrees C/ min) gave melting transitions at 153.6 and 139.8 degrees C, respectively, indicating disordering of fairly thermostable regions. This heating to high temperatures was accompanied by a partial thermal degradation of the linear amylose and RS chains. Reappearance of endotherms during repeated heating and the appearance of exotherms during each cooling phase suggested (re)association of chains from the polymer melts of both amylose and RS. Association of amylose and RS chains appeared to start between 80-75 degrees C and 60-55 degrees C, respectively. Whereas interactions between the long amylose chains were reduced at cooling rates of > 10 degrees C/min, interchain contacts between the shorter RS chains seemed not to be affected by the rate of cooling. In the presence of the complexing agent L-alpha-lysophosphatidylcholine (LPC), the process of association of linear chains was competitively affected by the formation of inclusion complexes of the linear chains with LPC. At an LPC concentration of 10% (w/w), complex formation dominated, and no association of amylose or RS chains was observed.
ABSTRACT: Optimal sterilization temperatures are defined as the processing temperatures which result in a minimum surface cook-value after achieving the desired degree of sterility. They were calculated as a function of product heating rate, surface heat transfer coefficient, initial food temperature, heating medium come-up-time, z-value for the quality factor and target Fo-value. Different one-dimensional heat transfer shapes were considered. Compared to the other variables, initial temperature and heating medium come-up-time had little influence on optimal processing temperature. Regression equations were developed relating optimal temperatures with all relevant variables.
ABSTRACT: In order to quantify the effect of heating rate on the thermal inactivation of Listeria monocytogenes an accurate means of describing the inactivation kinetics at near instantaneous heating was used. Survivor curves for L. monocytogenes, at near instantaneous heating, were obtained over the temperature range 50-64 degrees C. The use of a linear function to describe the data would have given only a poor approximation of the true inactivation kinetics. With a model based on a logistic algorithm extremely accurate descriptions were made. In processes which had rates of heating less than or equal to 50 degrees C min-1, significant deviations of real kill from predicted kill were observed. Predicted kill assumed that heating rate did not affect the inactivation kinetics of a thermal process. At rates of heating between 5.0 and 0.7 degrees C min-1 the deviation greatly increased as the rate of heating decreased; approximately a 1.7 X 10(5)-fold difference at 0.7 degrees C min-1. Maximum thermotolerance was induced at rates of heating less than or equal to 0.7 degrees C min-1. The increased thermotolerance during slow rates of heating was analogous to the induction of the heat-shock response. The models described in this work allow for confident assessments of safety to be made not only at near instantaneous heating but also when the heating rate varies. .
ABSTRACT: When fresh duck (Anas plotyrhyncus) eggs (pH 8.0-8.5) are heated, their albumen develops a turbid gel. Through appropriate alkalisation (pH 11.5-12.8), the gel's transparency can be increased. The transparency of the heated duck eggwhite is affected by pH value, heating temperature, heating rate and salt concentration. This research deals with the process for preparing the transparent alkalised duck egg and the change in its quality when stored. If fresh duck eggs are pickled in a solution of 42 g NaOH + 50 g NaCl litre-1 (25 +/- 3 degrees C) for 8 days, removed, put in a water bath and heated at 70 degrees C for 10 min they become transparent, their hardness and penetration increasing with storage. Total bacterial count and volatile basic nitrogen also increase with storage. The total bacterial count and the volatile basic nitrogen were 4.6 X 10(6) cfu g-1, 0.32 mg g-1 when stored at a temperature of under 25 degrees C for 4 weeks, respectively.
ABSTRACT: A general dynamic mathematical model was developed to predict the effect of can arrangement geometry on temperature distribution within cans in still retorts. For this purpose, the temperature variation in the cans was recorded for various can arrangements. Also, the influence of the physical properties of the material and the mechanism of heat transfer for heat penetration were studied. Experiments were carried out with water, peas in brine and tomato paste in no. 3 cans in an experimental vertical still retort. The equations employed for modelling were elliptic partial differential equations. They were solved numerically on a microcomputer using the finite element method. .
ABSTRACT: A mathematical model of simultaneous heat and moisture transfer is proposed for the prediction of moisture and temperature distributions during drying in a slab-shaped solid. The model took into account the effect of moisture-solid interaction at the drying surface by means of sorption isotherms of food. Non-constant physical and thermal properties were also incorporated in the model. The model was applied to the air drying potatoes. A finite difference method (Crank-Nicolson) was used in the solution of simultaneous heat and moisture transfer equations at different times during drying. When the experimental results were compared with those obtained from the finite difference method, good agreement was found. AbstractA mathematical model, developed to predict available-lysine losses in a model food system which had undergone an isothermal-nonstirred process, was tested under different process conditions. The model predictions were compared to measured available-lysine losses in both jacketed-mixer processing and extrusion processing. Statistical analysis using a paired t-test analysis indicated a signficiant correlation between predicted and actual results for jacket-mixer process. In the extrusion experiment a statistically significant correlation (0.7) occurred when the predicted values were plotted against observed. However, variation due to product backmixing and inaccurate temperature measurement prevented a rigorous test of the model. The reaction order of available lysine loss in casein, single-cell protein and a soy protein isolate were determined at an elevated temperature. The casein and single-cell protein followed first-order reaction kinetics. The soy isolate initially follows first-order loss but after an approximate loss of 40-50% available lysine, the loss abruptly stops and a no-loss phase occurs.
ABSTRACT: The energetics of thermal denaturation of two isoforms of ribonuclease T1 (Gln25 and Lys25) in various solvents have been studied by differential scanning calorimetry. It has been shown that the thermal transition of both forms of RNase T1 is strongly affected by slow kinetics, which cause an apparent deviation of the transition from a simple two-state model. By decreasing the heating rate or increasing the transition temperature, the denaturation of RNase approaches an equilibrium two-state transition. This permits determination of the thermodynamic parameters characterizing unfolding of the native structure. These thermodynamic parameters were correlated with the structural features of protein. Analysis of different contributions to the stability of RNase T1 shows that van der Waals interactions and hydrogen bonding are the major contributors to the conformational stability of the protein. . A mathematical model of baking was set up and validated experimentally. The model describes heat and mass transport phenomena during baking of a cylindrical bread sample. The model was solved by finite difference numerical method. The model is based on the hypothesis described in a previous work (Zanoni, B., Peri, C. & Pierucci, S. (1993). J. Food Eng., 19, 383-98), that the variation in temperature and moisture of bread during baking is determined by the formation of an evaporation front at 100 degrees C. The progressive advancing of the evaporation front towards the inside of the product determines different conditions of heat and mass transport in a crust and crumb portion. The validation shows that the model correctly simulates heat and mass transfer during baking.
ABSTRACT: Heat penetration (HP) test data have been obtained for water in 13 sizes of metal cans and for 16 fluids with different physical properties in 211 x 400 metal cans. Data were collected until the slowest heating zone was less than 0.1 difference in temperature below the heating medium temperature. When conventional HP graphs were plotted, these natural convection heating liquids formed curves instead of straight lines. A straight line was fitted by least squares regression to the data between (T1 - T) values from 40.0 to 4.0, 10.0 to 1.0, 4.0 to 0.4, and 1.0 to 0.2 difference in temperature and the f-values determined. The results show that the f-value of fluids that heat by convection increase with heating time, indicating that the true shape of the heat penetration data on a semilogarithmic graph is a curve.
ABSTRACT: Heat penetration (HP) test data have been obtained for water in 13 sizes of metal cans and for 16 fluids with different physical properties in 211 X 400 metal cans. Data were coiiected until slowest heating zone was less than 0.1 C degrees below the he. 
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