BROWNING REACTIONS

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Return to Color Index
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Browning Colors
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Color Measurement
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Color Systems
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Maillard Reaction
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Phenolic Reaction
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FAQ - FREQUENTLY ASKED QUESTIONS to Top

Nonoxidative Browning to Top

It is thought that nonoxidative may involve enzymes in the initial step. It generally entails the releasing of reactive reducing sugars from their conjugates. This is seen in products such as honey, maple syrup, chocolate, dates, and vanilla.

Oxidation Browning to Top

In oxidative browning of the enzymic type, the oxidases are active only in the first conversion of phenol, enediol, or conjugated diene functional groups to reactive carbonyl compounds. The subsequent reactions may be become nonenzymic. This initial reaction can occur without the enzyme with slow oxidation. This type of reaction is seen in orange juice where it will turn a brownish color

Browning of Pears

Polyphenols, Polyphenoloxidase, and Enzymatic Browning

Browning of Bananas

Carmelization Reactions to Top

The fundamental reactions of heat-induced sugar caramelization includes a hydrolysis and dehydration of sugars, isomerization and dehydration and ultimately many polymers. The have been described indicated below
  • Inversion of sucrose to D-glucose and D-fructose.
  • Equilibration of anomeric and ring forms.
  • Condensation, intermolecular, i.e., acid-catalyzed reversion of starch sugars to di-, tri-, and higher oligosaccharides.
  • Condensation, intramolecular, i.e., formation of glycosans and difructose dianhydrides.
  • Isomerization of aldoses to ketoses
  • Dehydration reactions
  • Fragmentation reactions
  • Browning (formation of unsaturated polymers)
  • Sugar-Ammonia Reactions to Top

    The reactions of sugars with aqueous ammonia resemble both alkaline carmelization reactions and the sugar-amine (Maillard) reaction. Breakdown forms brown polymers.



    Sugar-Amine Reaction (MAILLARD REACTION)

  • Basic Reaction
  • Factors Affecting the Maillard Reaction
  • 1. Water content and water activity
    2. Type of Sugars and Amino Acids
    3. pH
    4. Inhibitors
    Browning Due to Phenolic Compound Oxidation to Top

    This is the type of browning primarily involved in the browning of apples, pears, peaches and other fruit. A thesis written by Connie Weaver has further information about this.

    Updated: Wednesday, October 24, 2007.

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