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REPRINTS, COPIES
Return to Color Index
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Browning Colors
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Color Measurement
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Color Systems
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Maillard Reaction
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Phenolic Reaction
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FAQ - FREQUENTLY ASKED QUESTIONS
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It is thought that nonoxidative may involve enzymes in the initial step.
It generally entails the releasing of reactive reducing sugars from their
conjugates. This is seen in products such as honey, maple syrup, chocolate,
dates, and vanilla.
In oxidative browning of the enzymic type, the oxidases are active only in the first conversion of phenol, enediol, or conjugated diene functional groups to reactive carbonyl compounds. The subsequent reactions may be become nonenzymic. This initial reaction can occur without the enzyme with slow oxidation. This type of reaction is seen in orange juice where it will turn a brownish color
- Browning of Pears
Polyphenols, Polyphenoloxidase, and Enzymatic Browning
Browning of Bananas
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Carmelization Reactions
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The fundamental reactions of heat-induced sugar caramelization includes
a hydrolysis and dehydration of sugars, isomerization and dehydration and
ultimately many polymers. The have been described indicated below
Inversion of sucrose to D-glucose and D-fructose.
Equilibration of anomeric and ring forms.
Condensation, intermolecular, i.e., acid-catalyzed reversion of starch sugars to di-, tri-, and higher oligosaccharides.
Condensation, intramolecular, i.e., formation of glycosans and difructose dianhydrides.
Isomerization of aldoses to ketoses
Dehydration reactions
Fragmentation reactions
Browning (formation of unsaturated polymers)
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Sugar-Ammonia Reactions
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The reactions of sugars with aqueous ammonia resemble both alkaline carmelization reactions and the sugar-amine (Maillard) reaction. Breakdown forms brown polymers.
Sugar-Amine Reaction (MAILLARD REACTION)
- Basic Reaction
- Factors Affecting the Maillard Reaction
- 1. Water content and water activity
2. Type of Sugars and Amino Acids
3. pH
4. Inhibitors
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Browning Due to Phenolic Compound Oxidation
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This is the type of browning primarily involved in the browning of apples, pears, peaches and other fruit. A thesis written by Connie Weaver has further information about this.
Updated: Wednesday, October 24, 2007. |